Table 4 Retention time, quantification and qualifying ions of cannabinoids and unknown compounds from 3.5 ± 0.1 mg trichome sample separated from the mixed inflorescences plant material with two different Cannabis sativa accessions (a chemotype I and a chemotype III)
Compound | Retention time (min) | Quantifier ion | Qualifier ions | Sample 1 (mg/kg) | Sample 2 (mg/kg) | Sample 3 (mg/kg) |
|---|---|---|---|---|---|---|
Unknown 1 | 5.80 | 333 | 333, 292 | – | – | – |
Unknown 2 | 5.86 | 313 | 328, 269 | – | – | – |
Cannabidivarin | 6.11 | 362 | 309, 273 | 229 | 294 | 244 |
Unknown 3 | 6.51 | 343 | 358, 315 | – | – | – |
Cannabidiol | 6.71 | 390 | 337, 301 | 3006 | 3657 | 3362 |
Cannabichromene | 7.04 | 303 | 246, 371 | 174 | 214 | 192 |
Unknown 4 | 7.07 | 318 | 303, 156 | – | – | – |
Δ8-tetrahydrocannabinol | 7.24 | 386 | 303, 330 | 7933 | 9733 | 8541 |
Δ9-tetrahydrocannabinol | 7.24 | 371 | 386, 315 | 7697 | 9431 | 8385 |
Unknown 5 | 7.45 | 303 | 318, 246 | – | – | – |
Unknown 6 | 7.49 | 474 | 391, 403 | – | – | – |
Cannabinol | 7.66 | 367 | 382, 310 | 275 | 368 | 313 |
Unknown 7 | 7.86 | 391 | 433, 474 | – | – | – |
Unknown 8 | 7.91 | 459 | 491, 559 | – | – | – |
Unknown 9 | 8.32 | 455 | 367, 293 | – | – | – |
Unknown 10 | 8.43 | 575 | 447, 500 | – | – | – |
Tetrahydrocannabinolic acid | 8.67 | 487 | 488, 502 | 149776 | 171757 | 179447 |
Unknown 11 | 8.90 | 503 | 413, 487 | – | – | – |
Unknown 12 | 9.12 | 483 | 395, 321 | – | – | – |
Unknown 13 | 9.34 | 419 | 156, 257 | – | – | – |
Unknown 14 | 9.49 | 501 | 519, 355 | – | – | – |