Table 3 Compound, retention time (min), quantification and qualifying ions of cannabinoids, and unknown compounds from 10.5 ± 0.3 mg of the mixed inflorescences plant material with a Cannabis sativa accession (chemotype III)
Compound | Retention time (min) | Quantifier ion | Qualifier ions | Sample 1 (mg/kg) | Sample 2 (mg/kg | Sample 3 (mg/kg) |
|---|---|---|---|---|---|---|
Unknown 1 | 5.68 | 313 | 117, 129 | – | – | – |
Cannabidivarin | 5.91 | 362 | 309, 273 | 2.6 | 2.6 | 1.6 |
Unknown 2 | 6.37 | 341 | 129, 145 | – | – | – |
Unknown 3 | 6.40 | 337 | 262, 129 | – | – | – |
Cannabidiol | 6.48 | 390 | 337, 301 | 301.5 | 196.0 | 186.3 |
Cannabigerol | 7.17 | 337 | 391, 460 | 6.5 | 4.5 | 4.3 |
Cannabichromene | 7.19 | 303 | 246, 371 | 42.3 | 28.2 | 26.5 |
Δ8-tetrahydrocannabinol | 7.47 (not detected) | 386 | 303, 330 | 1782.0 | 1096.3 | 996.3 |
Δ9-tetrahydrocannabinol | 7.59 | 371 | 386, 315 | 1730.9 | 1079.9 | 972.3 |
Cannabidiolic acid | 7.60 | 491 | 559, 453 | 1583.8 | 1095.3 | 987.6 |
Cannabinol | 8.14 | 367 | 382, 310 | 22.1 | 11.9 | 13.7 |
Cannabigerolic acid | 8.6 (trace) | 561 | 417, 453 | 16.3 | 15.1 | 11.2 |
Unknown 4 | 8.94 | 419 | 487, 257 | – | – | – |
Tetrahydrocannabinolic acid | 9.08 | 487 | 488, 502 | 9205.7 | 7354.1 | 6858.3 |
a5-alpha-cholestane | 10.46 | 217 | 357, 372 | – | – | – |