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Table 2 Compounds, retention time (min), quantifier and qualifier ions of Cayman Chemical Cannabinoid standard Mixture 10 (product code: 21305). Derivatisation groups as per Cardenia et al. (2018)

From: Semi-quantitative analysis of cannabinoids in hemp (Cannabis sativa L.) using gas chromatography coupled to mass spectrometry

Compound

Retention time (min)

Quantifier ion

Qualifier ions

Derivatisation group(s)

Cannabidivarin

5.91

362

309, 273

CBDV-1TMS

Cannabidiol

6.48

390

337, 301

CBD-2TMS

Cannabigerol

7.15

337

391, 460

CBG-2TMS

Cannabichromene

7.19

303

246, 371

CBC-1TMS

Δ8-tetrahydrocannabinol

7.47

386

303, 330

Δ8-THC-1TMS

Cannabidiolic acid

7.56

491

559, 453

CBDA-3TMS

Δ9-tetrahydrocannabinol

7.58

371

386, 315

Δ9-THC-1TMS

Cannabinol

8.14

367

382, 310

CBN-1TMS

Cannabigerolic acid

8.57

561

417, 453

CBGA-3TMS

Tetrahydrocannabinolic acid

9.08

487

488, 502

THCA-2TMS

a5-alpha-cholestane

10.48

217

357, 372

  1. aInternal standard